What are the common treatment methods for cyanide - containing waste liquid?

What are the common treatment methods for cyanide - containing waste liquid? Sodium Cyanide liquid Recycling No. 1picture

In the current context of continuously improving environmental management levels and increasingly stringent requirements, many fields that utilize cyanides generate a significant amount of harmful waste liquid. If not properly utilized, it can pose risks to human health. To achieve the dual goals of non - waste and non - harm, Recycling methods can be adopted to address this issue.

Acidification Method

The main principle of this method is to add sulfuric acid to cyanide - containing wastewater such as Sodium cyanide wastewater and adjust the pH to around 1.5. This converts CN - into HCN. Since the boiling point of HCN is extremely low, only 26.5℃, it can escape from the solution at room temperature. The escaped HCN gas is introduced into an absorber and absorbed by an alkaline solution (sodium hydroxide or calcium hydroxide solution). As a result, a 20% - 30% cyanide solution is obtained, which can be recycled.

Ion - Exchange Method

Anion - exchange resins have a strong affinity for various metal - cyanide complex ions in cyanide - containing wastewater. Through the processes of adsorption and desorption, Cyanides and valuable metals in the wastewater can be removed. The advantage of this method is that the purified water quality is good and stable. However, anion - exchange resins have small particle sizes and insufficient mechanical strength. Moreover, the process is relatively complex, with high operation difficulty and high costs.

Activated Carbon Adsorption Method

Activated carbon has a rich microporous structure and surface hydrophobicity, and it has an extremely strong affinity for toxic substances in water. Therefore, the activated carbon adsorption method has always been one of the most effective methods for removing low - concentration toxic substances in water. The adsorption effect of activated carbon mainly depends on its numerous internal pores and large specific surface area.

To ensure that cyanides such as Sodium Cyanide have not leaked, inspectors regularly test the water quality to determine the scope of cyanide contamination. If necessary, the warning area is expanded. Both inspectors and on - site treatment personnel should wear rubber oil - resistant protective gloves.

In conclusion, proper treatment and recycling of Cyanide waste liquid are crucial for environmental protection and resource conservation. By implementing these methods and ensuring strict monitoring, we can minimize the negative impacts of cyanide - containing waste on the environment and human health.

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